Pie chart with specific color and position:

import numpy as np
import matplotlib.pyplot as plt

fig =plt.figure(figsize = (4,4))
ax11 = fig.add_subplot(111)
# Data to plot
labels = 'Python', 'C++', 'Ruby', 'Java'
sizes = [250, 130, 75, 200]
colors = ['gold', 'yellowgreen', 'lightcoral', 'lightskyblue']

# Plot
w,l,p = ax11.pie(sizes,  labels=labels, colors=colors,
                 autopct='%1.1f%%', startangle=140, pctdistance=1, radius=0.5)

pctdists = [.8, .5, .4, .2]

for t,d in zip(p, pctdists):
    xi,yi = t.get_position()
    ri = np.sqrt(xi**2+yi**2)
    phi = np.arctan2(yi,xi)
    x = d*ri*np.cos(phi)
    y = d*ri*np.sin(phi)
    t.set_position((x,y))

plt.axis('equal')
plt.show()