Add row at end:

import pandas as pd

employees = pd.DataFrame({
    'EmpCode': ['Emp001', 'Emp002', 'Emp003', 'Emp004', 'Emp005'],
    'Name': ['John', 'Doe', 'William', 'Spark', 'Mark'],
    'Occupation': ['Chemist', 'Statistician', 'Statistician',
                   'Statistician', 'Programmer'],
    'Date Of Join': ['2018-01-25', '2018-01-26', '2018-01-26', '2018-02-26',
                     '2018-03-16'],
    'Age': [23, 24, 34, 29, 40]})

print("\n------------ BEFORE ----------------\n")
print(employees)

employees.loc[len(employees)] = [45, '2018-01-25', 'Emp006', 'Sunny',
                                 'Programmer']

print("\n------------ AFTER ----------------\n")
print(employees)

C:\pandas>python example23.py
 
------------ BEFORE ----------------
 
   Age Date Of Join EmpCode     Name    Occupation
0   23   2018-01-25  Emp001     John       Chemist
1   24   2018-01-26  Emp002      Doe  Statistician
2   34   2018-01-26  Emp003  William  Statistician
3   29   2018-02-26  Emp004    Spark  Statistician
4   40   2018-03-16  Emp005     Mark    Programmer
 
------------ AFTER ----------------
 
   Age Date Of Join EmpCode     Name    Occupation
0   23   2018-01-25  Emp001     John       Chemist
1   24   2018-01-26  Emp002      Doe  Statistician
2   34   2018-01-26  Emp003  William  Statistician
3   29   2018-02-26  Emp004    Spark  Statistician
4   40   2018-03-16  Emp005     Mark    Programmer
5   45   2018-01-25  Emp006    Sunny    Programmer
 
C:\pandas>pep8 example23.py
 
C:\pandas>